Adsorption Mechanism and Kinetic Characterization of Bituminous Coal under High Temperatures and Pressures in the Linxing-Shenfu Area

The majority of coalbed methane(CBM) in coal reservoirs is in adsorption states in coal matrix pores. To reveal the adsorption behavior of bituminous coal under high-temperature and high-pressure conditions and to discuss the microscopic control mechanism affecting the adsorption characteristics, isothermal adsorption experiments under hightemperature and high-pressure conditions, low-temperature liquid nitrogen adsorption-desorption experiments and CO2 adsorption experiments were performed on coal samples. Results show that the adsorption capacity of coal is comprehensively controlled by the maximum vitrinite reflectance(Ro, max), as well as temperature and pressure conditions. As the vitrinite reflectance increases, the adsorption capacity of coal increases. At low pressures, the pressure has a significant effect on the positive effect of adsorption, but the effect of temperature is relatively weak. As the pressure increases, the effect of temperature on the negative effect of adsorption gradually becomes apparent, and the influence of pressure gradually decreases. Considering pore volumes of pores with diameters of 1.7-100 nm, the peak volume of pores with diameters 10-100 nm is higher than that from pores with diameters 1.7-10 nm, especially for pores with diameters of 40-60 nm, indicating that pores with diameters of 10-100 nm are the main contributors to the pore volume. The pore specific surface area shows multiple peaks, and the peak value appears for pore diameters of 2-3 nm, indicating that this pore diameter is the main contributor to the specific surface area. For pore diameters of 0.489-1.083 nm, the pore size distribution is bimodal, with peak values at 0.56-0.62 nm and 0.82-0.88 nm. The adsorption capability of the coal reservoir depends on the development degree of the supermicroporous specific surface area, because the supermicroporous pores are the main contributors to the specific pore area. Additionally, the adsorption space increases as the adsorption equilibrium pressure increases. Under the same pressure, as the maximum vitrinite reflectance increases, the adsorption space increases. In addition, the cumulative reduction in the surface free energy increases as the maximum vitrinite reflectance increases. Furthermore, as the pressure increases, the surface free energy of each pressure point gradually decreases, indicating that as the pressure increases, it is increasingly difficult to adsorb methane molecules.     

微生物勘探技术在潮汕坳陷油气勘探中的应用初探

东沙海域潮汕坳陷中生界研究程度相对较低,油气分布规律不明,为了加强对该区油气分布和富集规律的研究,针对潮汕坳陷西部地质目标首次应用微生物地球化学勘探技术(MGCE),探讨其含油气性。MGCE技术以轻烃微渗漏理论为基础,采用地质微生物学方法和地球化学方法检测研究区海底表层的微生物异常和吸附烃异常,预测研究区下伏地层中油气的富集区及其油气性质。检测结果显示研究区西部凹陷的斜坡区微生物异常呈块状发育,轻烃微渗漏强度变化大,可能为潜在油气富集区,酸解吸附烃成果显示可能的油气性质为干气和凝析油气。     

Study on the Anisotropy of the Underground Medium in Hohhot

In this paper, the data of earthquake events of magnitude M_S6.0 and above produced in Hohhot Seismic Station from 2008 to 2015 and the data of M_L ≥ 1.0 seismic events from 2015 to 2016 in Horinger Seismic Station and the surrounding mobile stations in southern Hohhot are selected. Using Splitlab and SAM software, the spin-correlation method, the least-energy method and the cross-correlation coefficient method are used to analyze the teleseismic and near-seismic phases (SKS, S). The results of this study are in good agreement with the results previously obtained by other researchers. The study of teleseismic SKS splitting reflects the characteristics of the anisotropy of the upper mantle beneath Hohhot, that is, the anisotropy of the upper mantle shows NW, which reflects "fossil" Anisotropy, mainly in the continental structure of stable units and preserves the history of mantle deformation information. The crustal anisotropy reflected by the near-earthquake S-wave splitting study is similar to that of the active fault zone, trending NE as a whole and is consistent with the tectonic stress field background of the northeastern margin of Ordos block.     

Focal Mechanism and Focal Depth of the May 22, 2016 MS4.6 Earthquake in Chaoyang, Liaoning

An earthquake with M_S4.6 occurred at 17:08 p.m., May 22, 2016 in Chaoyang County, Liaoning Province. We used the P-wave first motion method, TDMT method, and CAP method to determine the focal mechanisms and the PTD method and sPn-Pn method to determine the focal depth. The focal mechanism results of the three methods are consistent. The depth results of the CAP method, PTD method and sPn-Pn method are close. We used the double difference location method to relocate earthquakes in 2009-2016, and obtained the strikes and dip angles of the small earthquake distributions with the help of simulated annealing algorithm and gauss Newton algorithm fitting. According to the focal mechanism results, the depth results, the characteristics of small earthquake distributions and the structural characteristics of the source area, the seismogenic fault strike is NEE and the main pressure force direction is NNW. The earthquake focal mechanism is for a normal fault type with a little left-lateral strike slip motion.     

An acoustic-wave theory for casing bond evaluation using viscoelastic slip boundary modeling

Slip boundary condition is commonly utilized to model elastic wave propagation through layered earth media. The same approach is used here to characterize acoustic wave propagation along a cased borehole with various cement bond conditions. By modeling the cement layer between casing and formation as a viscoelastic slip interface with complex coupling rigidity parameters, one can not only reduce the complexity in the classical elastic wave modeling of the problem, but also efficiently model various complicated wave phenomena that are difficult for the existing modeling. More specifically, the new theory can well describe the effect of the cement bond condition change and the location of the change (i.e., whether it is in the first interface between casing and cement, or the second interface between cement and formation) on the acoustic waves, demonstrating the good modeling capability and predicting power. Application of the theory to field data shows that the theory can correctly model the acoustic wave characteristics and interpret the cement bond condition, thus providing a useful fundament theory for casing bond evaluation using acoustic logging.     

中国银行业基层网点的空间演化机制

中国银行业改革持续深化,不同类型银行的业务限制和地域限制逐步取消,银行间竞争日益激烈,重新调整网点布局已成为各家银行应对措施之一。重点关注2007—2016年中国银行业基层网点的空间演化路径,在借鉴演化经济地理研究中产业关联思想的基础上,提出地方产业基础的金融关联度和区域间投资的金融关联度两个重要变量,以此构建解释框架。考虑到中国银行业渐进式的改革历程,按银行所有制及银行规模分组进行比较分析。研究发现：① 地方银行市场竞争越激烈会显著提升产业基础、投资流向的金融关联度在银行网点布局决策中的重要性,银行网点会向金融关联度高的地区集聚;② 各影响因素的作用机制随地方银行市场环境和银行成长过程发生变化,表现出阶段性特征;③ 银行的个体异质性也是影响银行网点空间演化路径的因素之一。     

新元古代—寒武纪硫同位素异常事件(Yudomski事件)的起源与结束

新元古代晚期—寒武纪早期是地球历史演化的关键时期,整个生物圈、大气圈和水圈在此期间都发生了巨大的变化,海水成分在其间也发生了明显的变化。而石盐流体包裹体恰恰记录了该时段海水主要离子成分的转变:海水成分从新元古代晚期的“文石海”,快速转化为寒武纪的“方解石海”；同时海水中的碳、锶、硫同位素都发生了剧烈的改变,其中海水硫酸根的硫同位素从新元古代冰期前的20‰左右,迅速升高到新元古代冰期后的35‰左右,甚至可以到45‰,海相蒸发岩沉积中的硫酸盐沉积(主要是石膏、硬石膏)则直接记录了当时海水中硫酸根的硫同位素变化。现有研究表明,新元古代晚期——寒武纪时期的海相蒸发岩沉积记录了当时海洋中存在着地质历史时期最大的硫同位素异常,即“Yudomski事件”。塔里木盆地的寒武纪早期、中期蒸发岩记录了“Yudomski事件”的硫同位素异常高值(35‰左右,甚至更高),表明这一起源于新元古代晚期的同位素异常事件持续到了寒武纪的早期和中期；塔里木盆地奥陶纪早期的蒸发岩、鄂尔多斯盆地奥陶纪中期蒸发岩和美国Williston盆地奥陶纪晚期地层的蒸发岩的硫同位素数据相似,都在+25‰左右则记录了较低的海洋硫同位素值,表明起源于新元古代冰期之后的“Yudomski事件”的硫同位素异常,持续到了寒武纪的中期,而结束于寒武纪的晚期。     

国内盐湖卤水硼资源提取专利分析

基于中国盐湖硼资源开发动态,选择国家知识产权局专利数据,从盐湖卤水硼资源提取相关专利申请时间、地域分布、主要方法等方面进行分析。发现中国专利包含多种盐湖硼资源提取方法,并且逐步走向成熟,其中萃取法已成为研究重点。近期关于多种伴生资源综合开发的专利越来越受到关注。对国内盐湖硼资源提取技术后续开发和产业发展提出了建议。     

大功率高频电波加热电离层的非线性物理过程

地基大功率电波加热电离层是通过地基大功率短波发射机向电离层发射无线电波，通过波-粒和波-波的相互作用将无线电波的能量注入电离层.通过这种有目的可操控的方式改变电离层电子密度和温度的分布，可以深入研究电离层中等离子体能量和物质的非线性演化过程，特别是电离层电子的非平衡态分布和加速问题.本文通过对电离层加热中几个比较重要物理过程的评述，对过去20年来我国研究学者在这一研究方向上取得的重要进展进行了介绍.